• 文献标题:   Effective adsorption of 2,4-dichlorophenol on hydrogenated graphene: kinetics and isotherms
  • 文献类型:   Article
  • 作  者:   YUAN H, YU HT, LI XN, QUAN X
  • 作者关键词:   hydrogenated graphene, 2 4dcp, kinetic, isotherm
  • 出版物名称:   CHINESE SCIENCE BULLETIN
  • ISSN:   1001-6538 EI 1861-9541
  • 通讯作者地址:   Dalian Univ Technol
  • 被引频次:   1
  • DOI:   10.1007/s11434-014-0530-0
  • 出版年:   2014

▎ 摘  要

The effective adsorption capability of a hydrogenated graphene (H-Gr) was demonstrated. The H-Gr was firstly prepared by heating graphene (Gr) in a hydrogen flow at 1,000 A degrees C. The specific surface area, layer number, zeta potential, surface defects, surface compounds groups and elemental ratio of H-Gr were investigated. Taking 2,4-dichlorophenol as a target pollutant, the adsorption ability of H-Gr was evaluated. The results showed that the adsorption kinetics followed the pseudo-second-order equation well. For the adsorption isotherms, the equilibrium data of H-Gr were found to fit to Langmuir model, which was different from the Freundlich model of Gr. The adsorption capacity of H-Gr was high to 287.01 mg/g, almost three times as much as that of Gr, which was benefit from the increase of specific surface area and zeta potential. This work suggests that H-Gr may be a potential candidate for the adsorption of aromatic compounds from water and has great prospect for practical application.