• 文献标题:   Preparation and Characterization of Graphene Oxide/Polyaniline/Polydopamine Nanocomposites towards Long-Term Anticorrosive Performance of Epoxy Coatings
  • 文献类型:   Article
  • 作  者:   HUANG YY, ZHANG BR, WU J, HONG RY, XU JJ
  • 作者关键词:   polydopamine, polyaniline, graphene oxide, anticorrosion, polymer coating
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/polym14163355
  • 出版年:   2022

▎ 摘  要

To address the challenging issues of metal materials corrosion in industries, which has caused huge economic losses and security threats to many facilities in marine environments, functional polymer coatings have been widely used and regarded as one of the simplest and most effective methods to prevent such an undesirable event. In this study, a new type of coating filler consisting of graphene oxide/polyaniline/polydopamine (GO-PANI-PDA) nanocomposites has been successfully synthesized. The morphology, structure, composition, and corrosion resistance performance of the GO-PANI-PDA (GPP) nanocomposites were investigated via a series of characterization methods. The results from our electrochemical impedance spectroscopy, potentiodynamic polarization curve and salt spray experiment showed that the best corrosion resistance performance of the coating is from GPP 21 with the epoxy/GO-PANI:PDA ratio of 2:1, which exhibited a positive corrosion potential (-0.51 V) shift from epoxy/GO-PANI coating (-0.64 V). The corrosion current density (3.83 x 10(-8) A/cm(2)) of GPP 21 is nearly an order of magnitude lower than that of epoxy/GO-PANI (7.05 x 10(-7) A/cm(2)). The good anti-corrosion performance was fascinatingly observed in salt spray tests even without obvious corrosion phenomenon after 30 days of testing. Due to these remarkable properties, GPP nanocomposites can be an outstanding candidate for the rapid development of broadband shielding and anticorrosive materials.