▎ 摘　　要

Herein, a three-step approach toward a multi-layered porous PBC/graphene sandwich has been developed, in which the chemical bonding interactions have been successfully enhanced via esterification between the layers of pyrolyzed bacterial cellulose (PBC) and graphene. Such a chemically induced compatible interface has been demonstrated to contribute significantly to the mass transfer efficiency when the PBC/graphene sandwich is deployed as electrode material for both supercapacitors and lithium-sulfur batteries. The high specific capacitance of the supercapacitors has been increased by three times, to 393 F g(-1) at 0.1 A g(-1). A high initial discharge specific capacity (similar to 1100 mAhg(-1)) and high coulombic efficiency (99% after 300 cycles) of the rPG/S-based lithium-sulfur batteries have been achieved.