• 文献标题:   Laser-induced graphene as the microporous layer in proton exchange membrane fuel cells
  • 文献类型:   Article
  • 作  者:   TILIAKOS A, TREFILOV AMI, TANASA E, BALAN A, STAMATIN I
  • 作者关键词:   laserinduced graphene, laser patterning, laser pyrolysi, lowtemperature decal transfer, microporous layer, pem fuel cell
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Natl Inst Laser Plasma Radiat Phys INFLPR
  • 被引频次:   3
  • DOI:   10.1016/j.apsusc.2019.144096
  • 出版年:   2020

▎ 摘  要

Porous nanocarbons have been established as materials of choice in the manufacturing of microporous layers (MPLs) for proton-exchange membrane fuel cells (PEM FCs). However, obtaining mechanically and chemically stable materials at competitive yield-to-cost ratios still remains a critical objective, with pyrolytic techniques having shown great promise for bulk material production. A recent advancement in the field, the acclaimed laser-induced graphene (LIG) method employs low-cost industrial engravers for the laser pyrolysis of polymeric substrates into graphene-based foams with distinctive 3D porous networks. In this work, we apply the LIG method on polyimide precursors to obtain surface-patterned hydrophobic graphene foams, and we develop a low-temperature decal method (LTD-LIG) for the direct transfer of non-sacrificial platinum-coated LIG on Nafion (R) membranes to serve as the MPL in PEM FCs. Obtained by a readily scalable and inexpensive manufacturing method, the assembled LIG-based FC prototype overcomes the water management and mechanical stability problems typically encountered by graphene-based MPLs to present impeccable fuel crossover and power performance at 888.33 mW cm(-2) mg(-1) of anodic Pt load at 80 degrees C and 80% RH, delivering a 20% increase in power density compared to a reference FC bearing a commercial carbon black MPL assembled with the same loadings.