• 文献标题:   Ultra-stretchable graphene aerogels at ultralow temperatures
  • 文献类型:   Article
  • 作  者:   YANG GH, ZHANG XF, WANG RJ, LIU X, ZHANG JM, ZONG L, YANG HS
  • 作者关键词:  
  • 出版物名称:   MATERIALS HORIZONS
  • ISSN:   2051-6347 EI 2051-6355
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1039/d3mh00014a EA FEB 2023
  • 出版年:   2023

▎ 摘  要

Graphene aerogels (GAs) possess workable deformation and sensing properties at extreme temperatures. However, their poor tensile properties have restricted their applications in stretchable electronic devices, smart soft robots, and aerospace. Herein, an ultra-stretchable and elastic graphene aerogel with record elongation from -95% to 400% was achieved by constructing a highly crimped and crosslinked graphene network using a microbubble-filled GA precursor by a simple compress-annealing process. This conductive aerogel with near zero Poisson's ratio showed rubber-like but temperature-invariant elasticity from 196.5 degrees C to 300 degrees C, and special strain insensitivity from 50% to 400% tensile strain and high sensitivity below 50% tensile strain. Therefore, it can be used as a highly stretchable but strain-insensitive conductor under extreme environments, in which these polymer-based stretchable conductive materials are not workable. Moreover, this work provides new thoughts on constructing inorganic ultra-stretchable materials.