• 文献标题:   Bromination of Graphene: A New Route to Making High Performance Transparent Conducting Electrodes with Low Optical Losses
  • 文献类型:   Article
  • 作  者:   MANSOUR AE, DEY S, AMASSIAN A, TANIELIAN MH
  • 作者关键词:   graphene, few layers graphene, transparent conducting electrode, doping bromine
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   KAUST
  • 被引频次:   23
  • DOI:   10.1021/acsami.5b03274
  • 出版年:   2015

▎ 摘  要

The unique optical and electrical properties of graphene have triggered great interest in its application as a transparent conducting electrode material and significant effort has been invested in achieving high conductivity while maintaining high transparency. Doping of graphene has been a popular route for reducing its sheet resistance, but this has typically come at a significant loss in optical transmittance. We demonstrate doping of few layers graphene (FLG) with bromine as a means of enhancing the conductivity via intercalation without major optical losses. Our results demonstrate the encapsulation of bromine within the FLG, leading to air-stable transparent conducting electrodes with 5-fold improvement of sheet resistance reaching similar to 180 Omega/square at the cost of only 2-3% loss of optical transmittance. The remarkably low trade-off in optical transparency leads to the highest enhancements in the figure of merit reported thus far for FLG. Furthermore, we tune the work function by up to 0.3 eV by tuning the bromine content. These results should help pave the way for further development of graphene as a potential substitute to transparent conducting polymers and metal oxides used in optoelectronics, photovoltaics, and beyond.