• 文献标题:   Exploration on reduced graphene oxide/strontium pyro niobate electrode material for electrochemical energy storage applications
  • 文献类型:   Article
  • 作  者:   KUMAR MIS, KIRUPAVATHY SS, SHALINI S
  • 作者关键词:   hummer #8217, s method, hydrothermal method, nanocomposite, columbite, electrochemical studie, impedance spectroscopy
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1007/s42823-020-00203-4 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Most recently, graphene-related composite-modified electrode surfaces are been widely employed to improve surface interactions and electron transfer kinetics. Hydrothermally prepared strontium pyro niobate (SPN) and reduced graphene oxide/strontium pyro niobate (RGOSPN) nanostructures reveal excellent morphology. X-ray diffraction analysis of SPN and RGOSPN agree with standard data. Thermogravimetry-differential scanning calorimetry analyses show that RGOSPN has higher thermal stability than SPN. In addition, from the polarization-electric field (P-E) loop measurements, the estimated value of remnant polarization (P-r) and coercive electric field (E-c) of SPN are 0.039 mu C cm(-2) and - 2.90 kV cm(-1) and that of RGOSPN nanocomposite are 0.0139 mu C cm(-2) and - 2.04 kV cm(-1). Cyclic voltammetry measurements show that RGOSPN nanocomposite manifests the possibility of electrochemical reversibility beyond long cycles without change in performance. The redox cycle reveal that RGOSPN can be used as part of a composite electrode for hybrid capacitors dynamic conditions. Moreover, the specific capacitance of SPN and RGOSPN was calculated using galvanostatic charge-discharge (GCD) technique. The observed energy density of 9.1 W h kg(-1) in RGOSPN is higher when compared with previous reported values.