• 文献标题:   Graphene oxide supported sodium stannate lithium ion battery anodes by the peroxide route: low temperature and no waste processing
  • 文献类型:   Article
  • 作  者:   MIKHAYLOV AA, MEDVEDEV AG, MASON CW, NAGASUBRAMANIAN A, MADHAVI S, BATABYAL SK, ZHANG Q, GUN J, PRIKHODCHENKO PV, LEV O
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   20
  • DOI:   10.1039/c5ta04514b
  • 出版年:   2015

▎ 摘  要

Since there has been a notable improvement in the performance of graphene-supported tin-based lithium ion battery anodes, they have become a viable alternative to state of the art graphite anodes. However, currently these anodes are produced by energy-demanding thermal processes and generate lithium chloride or other wastes. In this research, we demonstrate the formation of efficient and stable lithium ion battery anodes based on sodium stannate-coated reduced graphene oxide. Coating is performed at low temperatures and when a sodium peroxostannate precursor is used, the process can be carried out with zero waste discharge. Thermal treatment is required only for the solid material. The anode exhibited a charge capacity of 610 mA h g(-1) after 140 cycles at 100 mA g(-1). This is the first characterization of a sodium stannate-based anode for LIBs.