• 文献标题:   Graphene Oxide as a High-Performance Fluid-Loss-Control Additive in Water-Based Drilling Fluids
  • 文献类型:   Article
  • 作  者:   KOSYNKIN DV, CERIOTTI G, WILSON KC, LOMEDA JR, SCORSONE JT, PATEL AD, FRIEDHEIM JE, TOUR JM
  • 作者关键词:   graphene oxide, drilling fluid, shear thinning, oil well
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Rice Univ
  • 被引频次:   79
  • DOI:   10.1021/am2012799
  • 出版年:   2012

▎ 摘  要

Graphene oxide (GO) performs well as a filtration additive in water-based drilling fluids at concentrations as low as 0.2 % (w/w) by carbon content. Standard American Petroleum Institute (API) filtration tests were conducted on pH-adjusted, aqueous dispersions of GO and xanthan gum. It was found that a combination of large-flake GO and powdered GO in a 3:1 ratio performed best in the API tests, allowing an average fluid loss of 6.1 mL over 30 min and leaving a filter cake, similar to 20 mu m thick. In comparison, a standard suspension (similar to 12 g/L) of clays and polymers used in the oil industry gave an average fluid loss of 7.2 mL and a filter cake similar to 280 mu m thick. Scanning electron microscopy imaging revealed the extreme pliability of well-exfoliated GO, as the pressure due to filtration crumpled single GO sheets, forcing them to slide through pores with diameters much smaller than the flake's flattened size. GO solutions also exhibited greater shear thinning and higher temperature stability compared to clay-based fluid-loss additives, demonstrating potential for high-temperature well applications.