• 文献标题:   Graphene Field-Effect Transistor as a High-Throughput Platform to Probe Charge Separation at Donor-Acceptor Interfaces
  • 文献类型:   Article
  • 作  者:   KATTEL B, QIN L, KAFLE TR, CHAN WL
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • ISSN:   1948-7185
  • 通讯作者地址:   Univ Kansas
  • 被引频次:   3
  • DOI:   10.1021/acs.jpclett.8b00335
  • 出版年:   2018

▎ 摘  要

In organic and low-dimensional materials, electrons and holes are bound together to form excitons. Effective exciton dissociation at interfaces is essential for applications such as photovoltaics and photosensing. Here, we present an interface-sensitive, time-resolved method that utilizes graphene field effect transistor as an electric-field sensor to measure the charge separation dynamics and yield at donor-acceptor interfaces. Compared to other interface-sensitive spectroscopy techniques, our method has a much reduced measurement time and can be easily adapted to different material interfaces. Hence, it can be used as a high throughput screening tool to evaluate the charge separation efficiency in a large number of systems. By using zinc phthalocyanine/fullerene interface, we demonstrate how this method can be used to quantify the charge separation dynamics and yield at a typical organic donor-acceptor interface.