▎ 摘　　要

We report a facile bottom-up approach for the synthesis of pure and macro-sized (> 500 nm) graphene-like carbon by precisely employing sp(2) carbon rich 1,2,4,5-benzene tetracarboxylic acid (BTCA) as a precursor. We also addressed the features, such as high specific surface area (SSA) and sp(2) hybridized carbon content, of the BTCA-derived carbon (BTCADC) over conventional top-down processed reduced graphene oxide (RGO). For instance, a two fold enhancement in SSA (960 m(2) g(-1)) and C : O atomic ratio (similar to 19) was noted for BTCADC when compared to RGO (SSA: 402 m(2) g(-1) and C : O ratio similar to 10). The SSA of BTCADC was further extended to 2673 m(2) g(-1) via a chemical activation process (A-BTCADC) along with a high pore volume (2.15 cm(3) g(-1)). Furthermore, we attempted to explain the unsolved issue of carbon layer stacking (pi-pi stacking) in RGO by precisely adopting a bottom-up approach. From an application point of view, we explored the possibility of using such carbonaceous materials as promising electrodes for both symmetric and Li-ion hybrid supercapacitor configurations in an organic medium. The A-BTCADC based symmetric cell in a 1 M tetraethylammonium tetrafluoroborate (TEA.BF4) in acetonitrile (ACN) electrolyte displayed a specific capacitance (C-sp) of 225 F g(-1) (at 0.5 A g(-1)) with a stable cycling profile of up to 10 000 cycles (at 10 A g(-1)) between 0 and 3 V. This bottom-up approach opens new avenues to extend graphene-based science and technology to the next level.