▎ 摘　　要

In order to enhance the luminescent thermal stability and water resistance of K2SiF6:Mn4+, we proposed a simple hydrothermal method to synthesize K2SiF6:0.06Mn4+@GE-GQDS (6 mg/mol) (GE-GQDs: green emission graphene quantum dots) red emitting phosphor with outstanding water resistance. The emission intensity of the sample coated with the GE-GQDs still maintains 87.74% of the initial one after immersion for 360 min, while the uncoated K2SiF6:0.06Mn4+ sharply decreases to 11.26%. Another impressive phenomenon is that due to the negative thermal quenching (NTQ) effect, the luminescent thermal stability of the coated sample is also significantly improved, and the integrated photoluminescence (PL) intensity at 180 degrees C is 238% of that at 25 degrees C. In the meantime, the integrated PL intensity of the coated samples is 2.55 times that of K2SiF6:0.06Mn4+ under room temperature. Based on experimental results, it is suggested that after coating with GE-GQDs, a surface protective layer is formed on the surface of the sample, which improves the water resistance, room temperature emission intensity, and luminescent thermal stability of the coated sample. Finally, the improvement mechanism of the above multiple enhancements on luminescent properties is discussed and proposed. The above multiple enhancement effects make the sample have broad application for blue light-based warm and high-power WLEDs (white light-emitting diodes).