• 文献标题:   Investigation of the optimal weight contents of reduced graphene oxide-gold nanoparticles composites and theirs application in electrochemical biosensors
  • 文献类型:   Article
  • 作  者:   BAI XY, SHIU KK
  • 作者关键词:   reduced graphene oxide, au nanoparticle, weight ratio, composite material, electrochemical biosensor
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Hong Kong Baptist Univ
  • 被引频次:   13
  • DOI:   10.1016/j.jelechem.2014.03.031
  • 出版年:   2014

▎ 摘  要

Graphene, as a single-atom-thick carbon material, is considered an ideal platform for designing composite nanomaterials for high-performance electrochemical or electrocatalytic devices. Reduced graphene oxide-gold nanoparticles composites were prepared by depositing gold nanoparticles (AuNPs) on the surface of reduced graphene oxide (RGO) with different RGO-to-AuNPs weight ratios. The resulting composite materials were characterized morphologically and optically by scanning electron microscopy (SEM) and UV-visible absorption spectroscopy. Cyclic voltammetry and amperometric measurements were employed to investigate the electrocatalytic effect of different composites toward the reduction of hydrogen peroxide. Experimental results demonstrated that RGO-AuNPs composites displayed high stability and catalytic effect for the analysis of hydrogen peroxide, demonstrating the possible synergistic effects of the RGO-AuNPs composite materials. Additionally, direct electron transfer of glucose oxidase (GOD) was achieved after codeposition of GOD and chitosan (CHIT). The glassy carbon electrode modified with RGO-AuNPs/CHIT-GOD material exhibited an excellent catalytic effect for glucose detection with a sensitivity of 34 mA M-1 cm(-2) at a detection potential of -0.3 V vs. Ag\AgCl reference. (C) 2014 Elsevier B.V. All rights reserved.