• 文献标题:   A non-enzymatic amperometric glucose sensor based on the use of graphene frameworks-promoted ultrafine platinum nanoparticles
  • 文献类型:   Article
  • 作  者:   ZHU YY, ZHANG X, SUN JM, LI M, LIN YL, KANG K, MENG Y, FENG ZL, WANG J
  • 作者关键词:   electrochemical sensor, electrocatalytic activity, 3d structure, electrochemical active surface, cyclic voltammetry, electrochemical impedance spectroscopy, chronoamperometry, electrocatalytic oxidation, serum analysi
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Hebei Med Univ
  • 被引频次:   6
  • DOI:   10.1007/s00604-019-3653-9
  • 出版年:   2019

▎ 摘  要

Ultrafine platinum nanoparticles are grown on a 3D graphene framework (GF-Pt) via a hydrothermal method. The material, when placed on a glassy carbon electrode (GCE), displays enhanced electrocatalytic activity towards glucose oxidation. This is assumed to be the result of the numerous easily accessible active sites, an enlarged electrochemically active area, and the presence of multiple electron/ion transport channels. The modified GCE can be operated at a low potential (-0.15 V vs. Ag/AgCl) has linear responses in the 0.1 mu M-0.01 mM and 0.01 mM-20 mM glucose concentration range, and a 30 nM detection limit. It was applied to the rapid determination of glucose in human serum samples.