▎ 摘　　要

By coupling alpha-Fe2O3 with a 3D graphene inverse opal (3D-GIO) conducting electrode, the short diffusion length of carriers and low absorption coefficient in alpha-Fe2O3 for photoelectrochemical applications were successfully addressed. GIO was directly grown on FTO substrate under low temperature conditions, removing the need for a graphene transfer process. alpha-Fe2O3 nanoparticles (NPs) were hydrothermally deposited on the surface of GIO, creating alpha-Fe2O3/GIO. The photocurrent density of alpha-Fe2O3/GIO in water splitting reactions reached 1.62 mA/cm(2) at 1.5 V vs RHE, which is 1.4 times greater than that of optimized alpha-Fe2O3. The EIS and IPCE data confirm reduced electronhole recombination and fast electron transfer processes due to the short distance between active materials and the conducting electrode in the alpha-Fe2O3/GIO system. Our result may pave the way for designing devices in advanced energy conversion applications as well as a high efficiency hematite-based PEC system.