• 文献标题:   Click' Preparation of CuPt Nanorod-Anchored Graphene Oxide as a Catalyst in Water
  • 文献类型:   Article
  • 作  者:   YANG H, KWON Y, KWON T, LEE H, KIM BJ
  • 作者关键词:   click chemistry, graphene oxide, nanorod, cupt, catalysi
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   28
  • DOI:   10.1002/smll.201201002
  • 出版年:   2012

▎ 摘  要

In this paper, a simple and powerful method of producing nanoparticle-anchored graphene oxide (GO) composites using a click reaction is demonstrated. This method affords a facile means of anchoring of nanoparticles with various shapes and sizes on the GO. CuPt nanorods with controlled size, aspect ratio (from 1 to 11), and uniformity are synthesized. Transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy measurements are made to monitor the formation and characterize the properties of the CuPt nanorod-grafted GO composites. Their catalytic properties in the water phase are investigated using an o-phenylenediamine oxidation reaction. The results of this study clearly demonstrate that nonpolar CuPt nanorods immobilized on GO can function as a catalyst in an aqueous solution and that GO can be used as a catalytic nanorod support.