• 文献标题:   Fluorinated graphene oxide for enhanced S and X-band microwave absorption
  • 文献类型:   Article
  • 作  者:   SUDEEP PM, VINAYASREE S, MOHANAN P, AJAYAN PM, NARAYANAN TN, ANANTHARAMAN MR
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Cochin Univ Sci Technol
  • 被引频次:   38
  • DOI:   10.1063/1.4922209
  • 出版年:   2015

▎ 摘  要

Here we report the microwave absorbing properties of three graphene derivatives, namely, graphene oxide (GO), fluorinated GO (FGO, containing 5.6 at. % Fluorine (F)), and highly FGO (HFGO, containing 23 at. % F). FGO is known to be exhibiting improved electrochemical and electronic properties when compared to GO. Fluorination modifies the dielectric properties of GO and hence thought of as a good microwave absorber. The dielectric permittivities of GO, FGO, and HFGO were estimated in the S (2 GHz to 4 GHz) and X (8 GHz to 12 GHz) bands by employing cavity perturbation technique. For this, suspensions containing GO/FGO/HFGO were made in N-Methyl Pyrrolidone (NMP) and were subjected to cavity perturbation. The reflection loss was then estimated and it was found that -37 dB (at 3.2 GHz with 6.5mm thickness) and -31 dB (at 2.8 GHz with 6mm thickness) in the S band and a reflection loss of -18 dB (at 8.4 GHz with 2.5mm thickness) and -10 dB (at 11 GHz with 2mm thickness) in the X band were achieved for 0.01 wt.% of FGO and HFGO in NMP, respectively, suggesting that these materials can serve as efficient microwave absorbers even at low concentrations. (C) 2015 AIP Publishing LLC.