• 文献标题:   Preparation of graphene-modified PLA/PBAT composite monofilaments and its degradation behavior
  • 文献类型:   Article
  • 作  者:   LIU WY, ZHANG ST, YANG KJ, YU WW, SHI JA, ZHENG Q
  • 作者关键词:   graphene, pla, pbat, monofilament, compatibility, degradation behavior
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH TECHNOLOGYJMR T
  • ISSN:   2238-7854 EI 2214-0697
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.jmrt.2022.08.125 EA SEP 2022
  • 出版年:   2022

▎ 摘  要

The graphene-modified composite poly(lactic acid) (PLA)/poly(butylene adipate-coterephthalate) (PBAT) monofilaments were prepared by melt spinning. The effects of graphene (GR) contents on the microstructural, thermal, dynamic mechanical, and mechanical properties and the degradation behavior of the graphene-modified composite PLA/ PBAT monofilaments were studied. Scanning electron microscopy (SEM) confirmed the improved compatibility of the PLA particles in the PBAT matrix, while the transmission electron microscopy (TEM) demonstrated the size and morphology of the GR distribution in the polymer. As the GR content increased, dynamic mechanical analysis (DMA) clarified a decrease of the difference of glass transition temperature (Tg) between PLA and PBAT. In addition, the mechanical properties of the composite monofilaments were significantly enhanced at a GR content of 0.2 wt%. Weight loss rate of the composite monofilaments under soil and sea degradation conditions were obviously related to the GR content.(c) 2022 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).