• 文献标题:   Biodegradable blends of graphene quantum dots and thermoplastic starch with solid-state photoluminescent and conductive properties
  • 文献类型:   Article
  • 作  者:   CHEN J, LONG Z, WANG SF, MENG YH, ZHANG GL, NIE SX
  • 作者关键词:   thermoplastic starch, graphene quantum dot, solidstate photoluminescence, conductive property, film
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:   Jiangnan Univ
  • 被引频次:   2
  • DOI:   10.1016/j.ijbiomac.2019.07.211
  • 出版年:   2019

▎ 摘  要

Polymer composites based on blends of graphene quantum dots (GQDs) with thermoplastic starch (TPS) were prepared by melt-extrusion combined with hot pressing. The GQDs/TPS films were characterized as potential novel, high-performance, and ecofriendly composites replacing traditional non-biodegradable plastic packaging materials. GQDs stock solutions of different concentrations were incorporated into TPS matrices in order to analyze the solid-state fluorescent properties and conductive properties of GQDs/TPS films. The fluorescent, conductive, morphological, mechanical, and optical properties of the GQDs/TPS films were characterized by ultraviolet-visible spectroscopy, surface resistance measurement, scanning electron microscopy, Fourier-transform infrared (FT-IR) spectroscopy, tensile testing, and X-ray diffraction (XRD). FT-IR studies indicated hydrogen bonding between the oxygen-containing groups on GQDs surfaces and the -OH groups in the TPS. The mechanical testing results showed the optimum GQDs loading of 10.9 wt% in the blend. XRD and TEM studies indicated uniform graphene dispersions in the TPS matrix for