• 文献标题:   Performance of boron-doped graphene aerogel modified gas diffusion electrode for in-situ metal-free electrochemical advanced oxidation of Bisphenol A
  • 文献类型:   Article
  • 作  者:   WU PP, ZHANG YM, CHEN Z, DUAN YX, LAI YX, FANG QL, WANG F, LI S
  • 作者关键词:   borondoped graphene aerogel, metalfree catalyst, gas diffusion electrode, bisphenol a
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   North China Elect Power Univ
  • 被引频次:   7
  • DOI:   10.1016/j.apcatb.2019.117784
  • 出版年:   2019

▎ 摘  要

Exploring the application of efficient metal-free catalysts in electrochemical advanced oxidation process (EAOPs) is of practical significance for environmental pollution treatment. Herein, the novel boron-doped graphene aerogel (BGA) modified gas diffusion electrode (GDEs) was prepared, characterized, and employed for bisphenol A (BPA) degradation in nonmetallic EAOPs. Boron doping could promote electrode property with a complete BPA removal within 60 min, which was attributed to the enhancement of H2O2 in-situ decomposition to center dot OH. An appropriate proportion of BGA (2.4%) represented more positive onset potential, favoring the remarkable improvement of oxygen reduction reaction (ORR) activity. The metal-free EAOPs on BGA-GDEs manifested smaller change in reaction rate (0.0952 min(-1)) compared with that of traditional Electro-Fenton (EF) process (0.19115 min(-1)) when the initial pH increased from 3.0 to 9.0, revealing that the catalytic activity of this metal-free system exhibited excellent stability over a wide pH range. In addition, the overwhelming superiority of stability was certified. Hence, the in-situ metal-free electrocatalysis on BGA-GDEs could be considered as an environment-friendly pollutant removal system without risk of metal contamination.