• 文献标题:   Manganese(II) enhanced fluorescent nitrogen-doped graphene quantum dots: a facile and efficient synthesis and their applications for bioimaging and detection of Hg2+ ions
  • 文献类型:   Article
  • 作  者:   YANG L, QIN AM, CHEN SP, LIAO L, QIN JK, ZHANG KY
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Guilin Univ Technol
  • 被引频次:   6
  • DOI:   10.1039/c7ra12133d
  • 出版年:   2018

▎ 摘  要

Manganese ion (Mn2+) bonded nitrogen-doped graphene quantum dots (Mn(II)-NGQDs) with water solubility have been successfully synthesized by a simple, one-pot hydrothermal carbonization, using sodium citrate, glycine and manganese chloride as raw materials. The photoluminescence (PL) characteristics of Mn(II)-NGQDs were studied in detail. The resulting Mn(II)-NGQDs show a remarkably enhanced PL intensity and quantum yield (QY = 42.16%) compared with the product without Mn(II)doped (named as NG, QY = 27.06%) and the product doped with other metal ions. The Mn(II)-NGQDs not only display low toxicity and high cellular uptake efficiency for fluorescence live cell imaging in biological evaluations but also exhibit a fast, highly selective and sensitive fluorescence quenching effect toward Hg2+ ions, with a detection limit of 3.4 x 10(-8) mol L-1.