• 文献标题:   Tailoring the electrical transport properties of ferromagnetic MnFe2O4 nanoferrite by graphene oxide: An experimental study
  • 文献类型:   Article
  • 作  者:   KIRAN, THAKUR N
  • 作者关键词:   nanocomposite, structural characterization, electrical propertie, impedance, mh curve
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.matchemphys.2022.126844 EA OCT 2022
  • 出版年:   2022

▎ 摘  要

Herein, MnFe2O4 (MFO)-Graphene Oxide (GO) composites have been synthesized by ultrasonication method with a variation of GO content from 0 to 40 wt%. The structural tests (XRD, FTIR, HRTEM, EDX, and Raman spectroscopy) prove that the composites have high purity, contain a variety of functional groups, and have phonon modes of both GO and MFO phases. The highest value of dielectric constant (epsilon ' = 1823 at 100 Hz, epsilon ' = 122 at 1 MHz) with low dielectric loss (tan delta = 4.83 at 100 Hz) is obtained for composite with 40 wt% of GO content. The composite having 20 wt% of GO content has the lowest leakage current density (J = 4.99 x 10-7 A/ cm2 at an applied electric field of 25 V/cm). The impedance study indicates the enhancement in charge transfer resistance in composites with the introduction of GO. The saturation magnetization (Ms) drops gradually from Ms = 38.28 emu/g for 0 wt% of GO to Ms = 24.10 emu/g for 30 wt% of GO and then rises to Ms = 25.64 emu/g at 40 wt% of GO content. The studied composites show the characteristics of a soft magnetic state with small values of coercivity (Hc