• 文献标题:   Synthesis of strontium chromate-nitrogen and sulfur co-doped graphene and its potential for electrochemical hydrogen storage
  • 文献类型:   Article
  • 作  者:   RAMEZANI Z, DEHGHANI H
  • 作者关键词:   monazite, strontium chromate, electrochemical hydrogen storage, doped graphene, chronopotentiometry
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.ijhydene.2021.10.057 EA DEC 2021
  • 出版年:   2022

▎ 摘  要

In the present study, monazite-type strontium chromate (SrCrO4) as a ternary metal oxide was prepared by the sol-gel method. Nitrogen and sulfur co-doped graphene decorated with SrCrO4 nanocrystals was synthesized successfully, and the electrochemical hydrogen storage performance of the SrCrO4 and its relative nanocomposites also were investigated by chronopotentiometry (CHP) technique. The effect of doped graphene as a substrate of the SrCrO4 sample on the improvement of the electrochemical hydrogen storage performance was considered as well. The SrCrO4-nitrogen and sulfur co-doped graphene (SrCrO4/NSG) displayed the highest discharge capacity in comparison to SrCrO4-reduced graphene oxide (SrCrO4/rGO), SrCrO4 calcined at 1000 degrees C (SrCrO4 (1000)) and SrCrO4 calcined at 800 degrees C (SrCrO4 (800)). Also, increasing the hydrogen storage capacity of the samples by repeating the cycles indicated the excellent cycle stability of the nanoparticles. In monazite-type structures, oxygen vacancies can be created by thermal treatment. Creating oxygen vacancies can improve redox reactions, which increase the conductivity of the samples and hydrogen storage capacity. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.