• 文献标题:   An ultrahigh volumetric capacitance of squeezable three-dimensional bicontinuous nanoporous graphene
  • 文献类型:   Article
  • 作  者:   QIU HJ, CHEN LY, ITO Y, KANG JL, GUO XW, LIU P, KASHANI H, HIRATA A, FUJITA T, CHEN MW
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   7
  • DOI:   10.1039/c5nr08852f
  • 出版年:   2016

▎ 摘  要

Graphene with a large specific surface area and high conductivity has a large specific capacitance. However, its volumetric capacitance is usually very low because the restacking of 2D graphene sheets leads to the loss of the large ion-accessible surface area. Here we report squeezable bicontinuous nanoporous nitrogen-doped graphene, which is extremely flexible and can tolerate large volume contraction by mechanical compression without the face-to-face restacking occurring. The compressed nanoporous N-doped graphene with a large ion accessible surface area and high conductivity shows an ultrahigh volumetric capacitance of similar to 300 F cm(-3) together with excellent cycling stability and high rate performance.