• 文献标题:   N-Heterocyclic Carbene-Palladium Complex onto Graphene Oxide and Poly (ethylene glycol) (PEG) Applied as Superior Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction in Water
  • 文献类型:   Article
  • 作  者:   HERAVI MM, ASADI S, CHOPANI SMH, JADERI E
  • 作者关键词:   conducting polymer, graphene oxide, heterogeneous catalyst, nheterocyclic carbene nhc, suzukimiyaura reaction
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Alzahra Univ
  • 被引频次:   1
  • DOI:   10.1002/aoc.5805 EA JUN 2020
  • 出版年:   2020

▎ 摘  要

Using polymeric nanocomposites incorporated Pd to promote C-C coupling reactions has been found as one of the most successful strategies. In this paper we apply graphene oxide (GO) as an efficient surface immobilized by water-soluble poly (ethylene glycol)-imidazole followed by introduction of PdCl(2)salt to obtain the desired catalyst. Catalytic performance of this composite was investigated in the Suzuki-Miyaura cross-coupling reaction under mild reaction conditions and superior results were obtained. The hydrophilic nature of the catalyst and well distribution of Pd lead to superior catalytic activity in water media. Moreover, the Suzuki-Miyaura reaction proceed successfully with excellent yield and short reaction time without any loss of activity even after seven consecutive reaction cycles.