• 文献标题:   Electrolytic exfoliation of few-layer graphene/sodium dodecylbenzenesulfonate for coin- and cylindrical-cell supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   LOMAS T, POOCHAI C, SUKJIT P, WASAPINYOKUL K, MENSING JP, TUANTRANONT A, SRIPRACHUABWONG C
  • 作者关键词:   graphene, sodium dodecylbenzenesulfonate, electrolytic exfoliation, supercapacitor
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.diamond.2023.110020 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Electrolytic exfoliation of graphite is a promising way to produce graphene quickly, inexpensively, and in an environmentally friendly manner. In this research, sodium dodecylbenzenesulfonate (SDBS), a commonly used anionic surfactant, was dissolved in 1 M H2SO4 to produce SDBS-graphene via electrolytic graphite exfoliation. The AFM analysis validated the thickness of few-layer of SDBS-graphene between 5 and 15 nm. Then, a symmetric coin-cell (CR2032) supercapacitor (SC) comprised of SDBS-graphene and rGO (synthesized via Hummer's method) was assembled with 0.5 M H2SO4 as an electrolyte. The highly exfoliated SDBS-graphene demonstrated a greater capacitive electrochemical response than rGO. The CV and GCD techniques revealed that the specific capacitance of SDBS-graphene was 150 F g- 1 at 0.25 A g- 1 with 20.4 Wh kg-1 of energy density and 494 W kg-1 of power density and that its percentage capacitive retention remained 95 % after 10,000 cycles at 3 A g- 1, compared to the specific capacitance of reduced graphene. In addition, a cylindrical cell SC (CR32650) with SDBS-graphene demonstrated a capacitance of 220 F at 100 mA, along with an energy density of 33 kWh and a power density of 55 kW. This suggests that exfoliated SDBS-graphene may be utilized in SCs with high efficiency and long-term durability.