• 文献标题:   Cobalt Hexacyanoferrate-modified Graphene Platform Electrode and Its Electrochemical Sensing toward Hydrogen Peroxide
  • 文献类型:   Article
  • 作  者:   ZHAO HC, ZHANG P, LI SH, LUO HX
  • 作者关键词:   chemical vapor deposition, graphene, cobalt hexacyanoferrate nanoparticle, chemically modified platform electrode, hydrogen peroxide
  • 出版物名称:   CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
  • ISSN:   0253-3820 EI 1872-2040
  • 通讯作者地址:   Renmin Univ China
  • 被引频次:   11
  • DOI:   10.1016/S1872-2040(17)61018-1
  • 出版年:   2017

▎ 摘  要

A large area graphene platform electrode (GPE) was fabricated by transferring chemical vapor deposition (CVD) grown graphene on Cu foils onto polyethylene terephthalate (PET) substrates with the aid of polymethyl methacrylate (PMMA). Cobalt hexacyanoferrate (CoHCF) was electrodeposited on GPE by cyclic voltammetry. The morphology and electrochemical properties of CoHCF/ GPE were studied by scanning electron microscope (SEM), electrochemical impedance spectroscopy (EIS) and the electrochemical measurements. The CoHCF/ GPE showed favorable sensing effect toward H2O2. A novel non-enzyme H2O2 sensor was constructed. Under the optimal experimental conditions, the proposed sensor responded to the addition of H2O2 very quickly (about 2 s) with a wide linear rang (0.005-1.2 mM) and a low detection limit (7.1 nM). This sensor was easy to be fabricated and showed excellent stability and anti-interference ability.