• 文献标题:   Microwave-induced preparation of porous graphene nanosheets derived from biomass for supercapacitors
  • 文献类型:   Article
  • 作  者:   LI T, MA R, XU XH, SUN SC, LIN JH
  • 作者关键词:   microwave radiation, black sesame, porous graphene nanosheet, supercapacitor
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:  
  • 被引频次:   13
  • DOI:   10.1016/j.micromeso.2021.111277 EA JUL 2021
  • 出版年:   2021

▎ 摘  要

Microwave radiation has attracted more attention because it can increase the degree of graphitization of carbon materials. In this study, the porous graphene nanosheets (PGNSs) derived from black sesame are prepared via microwave radiation. Compared with traditional carbonization, the PGNS-4 sample prepared via microwave radiation not only has a larger specific surface area (2414.5 m(2) g(-1)), micropore with proper diameter, an appropriate number of mesopores and macropores, but also shows a higher degree of graphitization. Microwave radiation facilitated the transformation of the local carbon crystal structure of the material, resulting in locally highly graphitized. As an electric double-layer capacitor (EDLC) electrode material, the PGNS-4 exhibits a high specific capacitance of 369 F g(-1) at 1.0 A g(-1), and 320 F g(-1) at 10.0 A g(-1). The assembled symmetrical device fabricated has a maximum energy density of 25.2 W h kg(-1). This study proposes microwave radiation is an ideal technique for synthesizing biomass-based porous graphene carbons, because of the high degree of graphitization, and the highly porous structure of the final product.