• 文献标题:   Electrochemical and electrocatalytic reaction characteristics of boron-incorporated graphene via a simple spin-on dopant process
  • 文献类型:   Article
  • 作  者:   JANG AR, LEE YW, LEE SS, HONG J, BEAK SH, PAK S, LEE J, SHIN HS, AHN D, HONG WK, CHA S, SOHN JI, PARK IK
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Univ Oxford
  • 被引频次:   4
  • DOI:   10.1039/c7ta09517a
  • 出版年:   2018

▎ 摘  要

Chemical doping is one of the most effective methods to tune the electrochemical properties of graphene. We report a simple and relatively low-temperature process for the fabrication of boron doped graphene by using a spin-on dopant (SOD) method. SOD-treated graphene was successfully doped with boron atoms at a temperature lower than 600 degrees C. The fabricated boron doped graphene exhibits a specific capacitance of 4 mF cm(-2), as well as a high-rate performance of 91.9% at 200 mV s(-1) as an electrode material for pseudo-capacitors. It also shows excellent oxygen reduction activity and durability with a current retention of 91.4% and methanol-tolerance properties. These features are beneficial for catalyst applications in the oxygen reduction reaction due to well-engineered boron sites with high electrical conductivity and many active sites for electrochemical reactions.