• 文献标题:   Enzymatic Biosensor Based on One-step Electrodeposition of Graphene-gold Nanohybrid Materials and its Sensing Performance for Glucose
  • 文献类型:   Article
  • 作  者:   MIAO KP, YAN L, BI R, MA XY
  • 作者关键词:   graphenegold hybrid material, onestep electrodeposition, enzyme, biosensor
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1002/elan.202100293 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

RGO/Au/Ni electrode was manufactured by a convenient, controllable, and environmental process, which was carried out by cyclic voltammetry (CV), and in this process, graphene-gold nanohybrid materials were simultaneously deposited on the nickel foam. Then the GOx was immobilized on the RGO/Au/Ni electrode by covalent bonding, and obtained the enzymatic biosensor. Scanning electron microscope (SEM) and Raman spectroscopy were adopted to confirm the microstructure of the fabricated RGO/Au/Ni electrode. Fourier transform infrared spectroscopy (FT-IR) was used to characterize the prepared enzymatic electrode. CV, chronoamperometry, and electrochemical impedance spectroscopy (EIS) were used to characterize the electrochemical performance of the fabricated enzymatic biosensor. It is found that AuNPs were well dispersed on the wrinkled RGO sheets, and the biosensor had a high sensitivity to glucose (32.83 mu A . mM(-1) . cm(-2)) with a wide linear range (0.15 similar to 26.15 mM), the strengths of anti-interference ability, good stability, and repeatability, etc.