▎ 摘　　要

The prospect of graphene-based shielding materials in the form of fillers is limited by the cumbersome preparation of graphene. Herein, defect-tunable porous graphene prepared by carbothermal shock using low-value sucrose as a precursor is proposed as an effective shielding filler. The resultant porous graphene exhibits 32.5 dB shielding efficiency (SE) and 2.5-18 GHz effective bandwidth at a mass loading of 20 wt%, competing with the shielding performance of graphene fillers prepared by other methods. Particularly, defect-rich graphene synthesized by increasing voltage and prolonging time shows increased electromagnetic (EM) wave absorption, echoing the current concept of green shielding. In addition, the strategy of controlling the discharge conditions to improve the absorption by the shield is developed in the terahertz band. The average SE and reflection loss of the samples in the THz band (0.2-1.2 THz) exhibit 40.7 and 15.9 dB at filler loading of 5 wt%, respectively, achieving effective shielding and absorption of THz waves. This work paves a new way for low-cost preparation of graphene for EM interference shielding fillers. Meanwhile, it supplies a reference for the shielding research of the upcoming applications integrating multiple EM bands (such as sixth-generation based integrated sensing and communication).