• 文献标题:   Facile synthesis of graphene oxide @ mesoporous carbon hybrid nanocomposites for lithium sulfur battery
  • 文献类型:   Article
  • 作  者:   BAO WZ, ZHANG ZA, CHEN W, ZHOU CK, LAI YQ, LI J
  • 作者关键词:   lithium sulfur battery, sulfur cathode, graphene oxide, carbonization
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   35
  • DOI:   10.1016/j.electacta.2014.02.043
  • 出版年:   2014

▎ 摘  要

We present a design and synthesis of a hierarchical architecture of graphene oxide @ mesoporous carbon (GO@Meso-C) using graphene oxide @ metal-organic framework hybrid materials (GO@MOF-5) as both the template and precursor. Active sulfur is encapsulated into the GO@Meso-C matrix prepared via carbonize GO@MOF-5 polyhedrons for high performance lithium sulfur battery. The initial and 100th cycle discharge capacity of GO@Meso-C/S sulfur cathode are as high as 1122 mAh g(-1) and 820 mAh g(-1) at a current rate of 0.2 C. The remarkably high special capacity and capacity retention rate indicate that the GO@Meso-C is a promising host material for the sulfur cathode in the lithium sulfur battery applications. (C) 2014 Elsevier Ltd. All rights reserved.