• 文献标题:   Stability and dynamics of small molecules trapped on graphene
  • 文献类型:   Article
  • 作  者:   ERNI R, ROSSELL MD, NGUYEN MT, BLANKENBURG S, PASSERONE D
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   2469-9950 EI 2469-9969
  • 通讯作者地址:   EMPA
  • 被引频次:   60
  • DOI:   10.1103/PhysRevB.82.165443
  • 出版年:   2010

▎ 摘  要

Chromatic and spherical aberration-corrected atomic-resolution transmission electron microscopy combined with density-functional theory calculations is employed to elucidate the stability and dynamics of admolecules on suspended graphene. The results presented provide evidence that the interaction between the molecules and hydrogen adatoms leads to a mutual trapping. These "symbiotic" configurations can explain the presence of stable admolecules on graphene at ambient temperature. It is proposed to exploit these configurations to functionalize and dope graphene.