• 文献标题:   Layer by layer inkjet printing reduced graphene oxide film supported nickel cobalt layered double hydroxide as a binder-free electrode for supercapacitors
  • 文献类型:   Article
  • 作  者:   LI XY, ZHAO YH, YU J, LIU Q, CHEN RR, ZHANG HS, SONG DL, LIU JY, WANG J
  • 作者关键词:   inkjet printing, electrochemical deposition, reduced graphene oxide ink, nickelcobalt layered double hydroxide, supercapactior
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   3
  • DOI:   10.1016/j.apsusc.2019.144872
  • 出版年:   2020

▎ 摘  要

In our works, the reduced graphene oxide (rGO) ink was prepared successfully. Then, the thin rGO film was fabricated by using inkjet printing method, which can act as a high-conductive supporter for anchoring more active materials. Hence, the Ni-Co LDH as a main active material was applied to enhance the electrochemical activity via one-step electrochemical deposition method. To further meet practice application, the electrochemical performances and mass loading of electroactive material were improved by repeating inkjet printing and electrochemical deposition method. The capacity of Ni-Co LDH/rGO/Ni-Co LDH/rGO is reached to 227 mAh g(-1) at 1.2 A g(-1), and the capacity value can remain 78.7% after charge-discharge 5000 cycles. The two-electrode supercapacitors were fabricated from the Ni-Co LDH/rGO/Ni-Co LDH/rGO as positive electrode and commercial active carbon as negative electrode. The improvements of electrochemical properties of Ni-Co LDH/rGO/Ni-Co LDH/rGO//AC can be achieved in energy density of 84.9 Wh kg(-1) and power density of 424 kW kg(-1).