• 文献标题:   Porous cobalt-nitrogen-doped hollow graphene spheres as a superior electrocatalyst for enhanced oxygen reduction in both alkaline and acidic solutions
  • 文献类型:   Article
  • 作  者:   YU QM, XU JX, WAN CY, WU CX, GUAN LH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   19
  • DOI:   10.1039/c5ta04852d
  • 出版年:   2015

▎ 摘  要

Porous cobalt-nitrogen-doped hollow graphene spheres were prepared by a template synthesis method. As a catalyst for the oxygen reduction reaction, they exhibit an excellent electrocatalytic activity, superior methanol tolerance and strong durability, not only in alkaline solution, but also in acidic solution. The unprecedented electrocatalytic performance of the catalyst is attributed to the well-defined morphology, high specific surface area (321 m(2) g(-1)), large pore volume (1.8 cm(3) g(-1)) and homogeneous distribution of cobalt-nitrogen active