▎ 摘　　要

Lithium-ion hybrid supercapacitors combining the advantages of Li-ion batteries and supercapacitors have been the subject of extensive interest in the field of energy storage because of their high energy density at high power density. Herein, we report reduced graphene oxide (rGO) cross-linked mesoporous T-Nb2O5 nanospheres (T-Nb2O5 MNSs/rGO) as high-performance Li+ intercalation pseudocapacitive material and mesoporous carbon-coated rGO (MC/rGO) as high-power electric double-layer capacitive material. The T-Nb2O5 MNSs/rGO anode material boasts a high reversible capacity of 181mAhg(-1) at a current density of 20mAg(-1), good cycle stability, with 85% capacity retention after 1000 cycles, as well as excellent rate capability. The MC/rGO cathode material delivers a large capacity of 110 and 86Fg(-1) at a current density of 500 and 10000mAg(-1) in organic electrolyte in the voltage range of 3-4.5V (vs. Li/Li+). The advanced Li-HSCs with a T-Nb2O5 MNSs/rGO anode combined with a MC/rGO cathode show the highest power density of 25600Wkg(-1) at 21Whkg(-1), which is much higher than that of similar Li-HSC systems previously reported. Furthermore, the Li-HSCs exhibit an excellent cyclability, with 82% capacitance retention after 4000 cycles.