• 文献标题:   Potassium terephthalate/graphene nanocomposite as advanced anode for low-cost Na-ion batteries
  • 文献类型:   Article
  • 作  者:   DENG QJ, FENG SS, TIAN CC, DING YC, YANG R, YAN YL, XU YH
  • 作者关键词:   naion batterie, potassium terephthalate, graphene, electrochemical behavior
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Xian Univ Technol
  • 被引频次:   1
  • DOI:   10.1016/j.jelechem.2018.09.020
  • 出版年:   2018

▎ 摘  要

Organic carbonyl compounds are regarded as the next-generation Na-ion competitors, but the high solubility into organic electrolyte and low electronic and ion conductivity limited their large-scale application. In this study, organic terephthalate potassium (K2TP) was newly introduced as an advanced anode for low cost Na-ion batteries. After in-situ synthesized with suitable graphene (25%wt), the as-prepared K2TP-25G nanocomposite can exhibit remarkable specific capacity of 135 mAh g(-1) at 1 C over 200 cycles with stable capacity retention, which is superior to reported organic anodes for Na-ion batteries. The excellent electrochemical behaviors are ascribed to its stable and spacious lattice structure, the low solubility in common organic electrolyte of K2TP, as well as the formed K2TP-25G nanocomposite which can efficiently enhance the electronic conductivity and shorten the Na-ion pathway. These results are of importance to look insight into new organic electrode materials design for energy storage.