• 文献标题:   Studying delta-MnO2/reduced graphene oxide composite cathode in a low-temperature and high-voltage-tolerant hybrid electrolyte for aqueous Mg-ion batteries
  • 文献类型:   Article
  • 作  者:   TSAI YR, CHEN TY, YANG ZQ, TSAI CC, HUANG YT, ANURATHA KS, LIN TW, SOFER Z, LIN JY
  • 作者关键词:   deltamno2, reduced graphene oxide, composite cathode, hybrid electrolyte, aqueous mgion batterie
  • 出版物名称:   2D MATERIALS
  • ISSN:   2053-1583
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1088/2053-1583/acb278
  • 出版年:   2023

▎ 摘  要

Optimization of the aqueous electrolyte concentration is a significant issue in the development of high-performance aqueous rechargeable magnesium ion batteries (MIBs). In this study, a novel magnesium ion-based hybrid electrolyte composed of 2 M magnesium sulfate (MgSO4)/2 M acetate (MgOAc) was designed, and its corresponding physiochemical properties were systemically investigated by simply tuning their molar ratios. Additionally, a delta-MnO2/reduced graphene oxide (rGO) composite cathode material was successfully synthesized and delivered a high specific capacity and excellent rate capability in the optimized hybrid electrolyte. The as-fabricated device based on the delta-MnO2/rGO composite cathode exhibited a high operating voltage of up to 2 V and delivered a maximum energy density of 29.8 Wh kg(-1) at the power density of 823 W kg(-1). More importantly, the device showed impressive discharge capacity and excellent cycling stability even at the low temperature of -20 & DEG;C. In view of the outstanding electrochemical properties of the delta-MnO2/rGO composite cathode in an optimized hybrid electrolyte of MgSO4/MgOAc, it could be regarded as a novel prototype for low-cost aqueous MIBs.