▎ 摘 要
The broad spectrum of chemical and electronic properties of 2D nanomaterials makes them attractive in a wide range of applications, especially in the context of printed electronics. Therefore, understanding the rheological properties of nanosheet suspensions is crucial for many additive manufacturing techniques. Here, we study the viscoelastic properties of aqueous suspensions of graphene oxide nanosheets. We show that in the gel phase, the magnitude of the elastic response and its scaling with volume fraction is independent of the lateral size of the particles and the interaction strength between them. We explain this behavior by modelling the elasticity of these gels as a crumpling phenomenon where the magnitude of the response is determined by the bending stiffness and thickness of the sheets. Due to their low bending stiffness these nanosheets crumple upon deformation and may therefore be considered soft colloids. Furthermore, we provide an explanation why the yield strain decreases with packing fraction for these gels.