▎ 摘 要
The evolution of newfangled supercapacitor electrode materials has always been a task full of opportunities and challenges. In this work, we synthesized amorphous Co2SiO4 nanobelts by a template method to construct the nanostructure and combined Co2SiO4 nanobelts with graphene oxide (GO) to improve their electrochemical properties. The one-dimensional nanostructure enhanced the transport of electrons along the long axis, which facilitated current collection during cycling, thereby improving the electrochemical performances. At the same time, GO not only formed a good charge-transfer network but also prevented the aggregation and accumulation of Co2SiO4 nanobelts. After optimizing the ratio of Co2SiO4 to GO in the composites, the specific capacitance of Co2SiO4/GO composites totaled 511 F g(-1) (332 C g(-1)) at 0.5 A g(-1), and the capacitance retention rate measured 84% after 10 000 cycles. The excellent electrochemical performances of Co2SiO4/GO composites were further demonstrated by assembling a hybrid supercapacitor (HSC) device. The HSC device was assembled by Co2SiO4/GO composites and activated carbon (AC) with the maximum specific capacitance of 229 mF cm(-2) (183 mC cm(-2)) at 3 mA cm(-2), and 49% initial capacitance was maintained after 5000 cycles. Furthermore, the HSC exhibited a maximum energy density of 0.41 W h m(-2) and a maximum power density of 96 W m(-2), demonstrating the potential of Co2SiO4 nanobelts/GO composites applied to hybrid supercapacitors.