• 文献标题:   Nitrogen- Doped Graphene Quantum Dots: "Turn-off" Fluorescent Probe for Detection of Ag+ Ions
  • 文献类型:   Article
  • 作  者:   TABARAKI R, NATEGHI A
  • 作者关键词:   nitrogengraphene quantum dot, silver, boxbehnken design, sensor, fluorescence, glucose
  • 出版物名称:   JOURNAL OF FLUORESCENCE
  • ISSN:   1053-0509 EI 1573-4994
  • 通讯作者地址:   Ilam Univ
  • 被引频次:   35
  • DOI:   10.1007/s10895-015-1714-y
  • 出版年:   2016

▎ 摘  要

Highly luminescent nitrogen-doped graphene quantum dots (N-GQDs) were prepared from glucose and ammonia as carbon and nitrogen sources, respectively. The N-GQDs showed a strong emission at 458 nm with excitation at 360 nm. The N-GQDs exhibited analytical potential as sensing probes for silver ions determination. Factors affecting the fluorescence sensing of Ag+ ions such as pH, N-GQDs concentration and incubation time were studied using Box-Behnken experimental design. The optimum conditions were determined as pH 7, N-GQDs concentration 1 mg/mL and time 60 min. It suggested that N-GQDs exhibited high sensitivity and selectivity toward Ag+. The linear range of N-GQDs and the limit of detection (LOD) were 0.2-40 mu M and 168 nM, respectively. The N-GQDs-based Ag+ ions sensor was successfully applied to the determination of Ag+ in tap water and real river water samples.