• 文献标题:   Silicone-Modified Graphene Oxide Fillers via the Piers-Rubinsztajn Reaction
  • 文献类型:   Article
  • 作  者:   ZHANG JF, LIANG S, YU LY, SKOV AL, ETMIMI HM, MALLON PE, ADRONOV A, BROOK MA
  • 作者关键词:   elastomer, filler, graphene oxide, piersrubinsztajn reaction, reductive silylation, reinforced silicone elastomer, silicone
  • 出版物名称:   JOURNAL OF POLYMER SCIENCE PART APOLYMER CHEMISTRY
  • ISSN:   0887-624X EI 1099-0518
  • 通讯作者地址:   McMaster Univ
  • 被引频次:   8
  • DOI:   10.1002/pola.28112
  • 出版年:   2016

▎ 摘  要

While graphene or graphene oxide can make significant improvements in the properties of a wide variety of polymeric materials, their incorporation can be challenged by incompatibility with the polymeric matrix. The modification of graphene oxide with silicones or silanes using the PiersRubinsztajn reaction improves dispersibility in nonpolar materials, including organic solvents and silicone pre- elastomers. A high loading (up to 10 wt %) of modified graphene oxide in silicone elastomers could be achieved, which resulted in enhanced mechanical performance and reduced gas permeability. (C) 2016 Wiley Periodicals, Inc.