• 文献标题:   Incorporating graphene oxide into lime solution: A study of flocculation and corresponding improvement
  • 文献类型:   Article
  • 作  者:   JING GJ, YE ZM, LU XL, WU JM, WANG SX, CHENG X
  • 作者关键词:   portland cement, reaction, lime, dispersion, superplasticizer
  • 出版物名称:   MATERIALES DE CONSTRUCCION
  • ISSN:   0465-2746 EI 1988-3226
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   0
  • DOI:   10.3989/mc.2018.05217
  • 出版年:   2018

▎ 摘  要

The dispersion behavior of graphene oxide in cement matrix is one important factor in enhancing cement performance. In this work, we investigated the dispersion of graphene oxide in cement by simulating alkaline environment with a solution of calcium hydroxide and studied the corresponding strategy of improving dispersion. The obtained results showed that graphene oxide would flocculate even if calcium hydroxide concentration was very low, which might be the main reason of the unstable properties of the graphene oxidedoped cement. In addition, we discovered that, compared to -OH group, the -COOH group and the long chain of polycarboxylate-based superplasticizer were more effective in delaying the flocculation of graphene oxide. Finally, we proposed a dispersion mechanism of polycarboxylate-based superplasticizer. The study provides inspiration for the design of graphene oxide-doped cement materials.