• 文献标题:   MoO2-graphene nanocomposite as anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   TANG QW, SHAN ZQ, WANG L, QIN X
  • 作者关键词:   moo2 nanoparticle, graphene, anode material, nanocomposite, lithium ion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   88
  • DOI:   10.1016/j.electacta.2012.06.093
  • 出版年:   2012

▎ 摘  要

MoO2-graphene composite was synthesized via a two-step of hydrothermal-calcination method. The morphology and structure of the products were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray power diffraction (XRD), and Raman spectroscopy. The content of the graphene in MoO2-graphene composite was examined by thermogravimetric (TG)-differential scanning calorimetry (DSC) analysis. The electrochemical performances of the products were examined by Galvanostatical charge-discharge method, cyclic voltammetry, and electrochemical impedance spectroscopy (EIS). When used as anode material for lithium ion batteries, the MoO2-graphene composite shows an enhanced cyclic performance and lithium storage property. The first discharge capacity of the composite can reach 674.4 mAh g(-1) with a reversible capacity of 429.9 mAh g(-1). Significantly, the composite can also deliver a reversible capacity of as high as 1009.9 mAh g(-1) after 60 charge/discharge cycles. (C) 2012 Elsevier Ltd. All rights reserved.