• 文献标题:   Fabrication and properties of reduced graphene oxide reinforced yttria-stabilized zirconia composite ceramics
  • 文献类型:   Article
  • 作  者:   SHIN JH, HONG SH
  • 作者关键词:   zro2, reduced graphene oxide, nanocomposite, spark plasma sintering
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   48
  • DOI:   10.1016/j.jeurceramsoc.2013.11.034
  • 出版年:   2014

▎ 摘  要

Fully dense yttria-stabilized zirconia (YSZ) ceramics reinforced with reduced graphene oxide (RGO) were fabricated by spark plasma sintering (SPS), and their electrical, thermal, and mechanical properties were investigated. Graphene oxide (GO) was exfoliated by a short sonification in dimethylformamide (DMF)/water solution and uniformly mixed with ZrO2 powders. The microstructure of the composites showed that undamaged RGO sheets were homogeneously distributed throughout matrix grains. The electrical conductivity of YSZ composites drastically increased with the addition of RGO, and it reached 1.2 x 10(4) S/m at 4.1 vol.%. However, the thermal diffusivity increased only 12% with RGO addition. The hardness decreased slightly with RGO addition, whereas the fracture toughness significantly increased from 4.4 to 5.9 MPa1/2. The RGO pull-out and crack bridging contributed to the improved fracture toughness. (C) 2013 Elsevier Ltd. All rights reserved.