• 文献标题:   Paper-based laser-induced graphene for sustainable and flexible microsupercapacitor applications
  • 文献类型:   Article
  • 作  者:   COELHO J, CORREIA RF, SILVESTRE S, PINHEIRO T, MARQUES AC, CORREIA MRP, PINTO JV, FORTUNATO E, MARTINS R
  • 作者关键词:   laserinduced graphene, paper electronic, microsupercapacitor, sustainable production method, flexible device
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1007/s00604-022-05610-0
  • 出版年:   2023

▎ 摘  要

Laser-induced graphene (LIG) is as a promising material for flexible microsupercapacitors (MSCs) due to its simple and cost-effective processing. However, LIG-MSC research and production has been centered on non-sustainable polymeric substrates, such as polyimide. In this work, it is presented a cost-effective, reproducible, and robust approach for the preparation of LIG structures via a one-step laser direct writing on chromatography paper. The developed strategy relies on soaking the paper in a 0.1 M sodium tetraborate solution (borax) prior to the laser processing. Borax acts as a fire-retardant agent, thus allowing the laser processing of sensitive substrates that other way would be easily destroyed under the high-energy beam. LIG on paper exhibiting low sheet resistance (30 omega sq(-1)) and improved electrode/electrolyte interface was obtained by the proposed method. When used as microsupercapacitor electrodes, this laser-induced graphene resulted in specific capacitances of 4.6 mF cm(-2) (0.015 mA cm(-2)). Furthermore, the devices exhibit excellent cycling stability (> 10,000 cycles at 0.5 mA cm(-2)) and good mechanical properties. By connecting the devices in series and parallel, it was also possible to control the voltage and energy delivered by the system. Thus, paper-based LIG-MSC can be used as energy storage devices for flexible, low-cost, and portable electronics. Additionally, due to their flexible design and architecture, they can be easily adapted to other circuits and applications with different power requirements.