• 文献标题:   Possible pitfall in sample preparation for SEM analysis - A discussion of the paper "Fabrication of polycarboxylate/graphene oxide nanosheet composites by copolymerization for reinforcing and toughening cement composites" by Lv et al.
  • 文献类型:   Article
  • 作  者:   CUI HZ, YAN XT, TANG LP, XING F
  • 作者关键词:   graphene oxide, cement hydration, calcium carbonate, crystal morphology, sample preparation
  • 出版物名称:   CEMENT CONCRETE COMPOSITES
  • ISSN:   0958-9465 EI 1873-393X
  • 通讯作者地址:   Shenzhen Univ
  • 被引频次:   10
  • DOI:   10.1016/j.cemconcomp.2016.12.007
  • 出版年:   2017

▎ 摘  要

This paper presents a discussion of the paper published by Lv et al. in Cement and Concrete Composites, 2016, 66: 1-9. The discussion is mainly focused on whether or not graphene oxide (GO) nanosheets can regulate formation of flower-like cement hydration crystals. Lv et al. in their paper proposed a regulation mechanism stating that GO nanosheets can control ettringite (AFt), monosulfate (AFm) and calcium hydroxide (CH) to form the flower-like and polyhedron crystals, whilst our experimental results show that there might be a possible pitfall in sample preparation for SEM analysis. It is here suggested that the main chemical components of flower-like and polyhedron crystals are calcium carbonates, which are not the products from cement hydration but from carbonation of cementitious hydrates. It is therefore suggested that further study is needed to verify the regulation mechanism of GO on cement hydration crystals proposed by Lv et al. in the discussed paper. (C) 2016 Elsevier Ltd. All rights reserved.