• 文献标题:   An efficient carbon catalyst supports with mesoporous graphene-like morphology
  • 文献类型:   Article
  • 作  者:   LIU DD, ZHANG JX, ZHANG C, LV MY, ZHANG XN, SONG HY, DU L, XUE M
  • 作者关键词:   carbon support, mesoporous carbon sheet, graphenelike, ndoped, ru loaded
  • 出版物名称:   JOURNAL OF POROUS MATERIALS
  • ISSN:   1380-2224 EI 1573-4854
  • 通讯作者地址:   South China Univ Technol
  • 被引频次:   0
  • DOI:   10.1007/s10934-017-0503-1
  • 出版年:   2018

▎ 摘  要

In this work, we report the synthesis of ordered mesoporous carbon sheets (OMCS) with graphene-like morphology and their applications as the support for electrocatalysts. This lamellar material exhibits uniform mesoporous channels and ease of modification by using different nitrogen sources, such as melamine, urea, and ammonia. Nitrogen-doping on this material leads to a high specific surface area of 761 m(2) g(-1) and uniform pores with a diameter of 9 nm. Electrochemical tests show that the N-doped OMCS possesses high catalytic activities on the oxygen reduction reaction, which can be attributed to the pyridinic-type and pyrrolic-type nitrogen activating nearby carbon atoms. In addition, we demonstrate that the unique physical structure and surface chemical properties of OMCS improve the dispersion and structure of supported metal Ru nanoparticles, which lead to enhance oxygen evolution reaction activity.