• 文献标题:   Metal-organic frameworks (MOFs) derived carbon-coated NiS nanoparticles anchored on graphene layers for high-performance Li-S cathode material
  • 文献类型:   Article
  • 作  者:   ZOU F, LIU KW, CHENG CF, JI YJ, ZHU Y
  • 作者关键词:   metalorganic framework, nis, graphene, lis battery
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Univ Akron
  • 被引频次:   0
  • DOI:   10.1088/1361-6528/abae9b
  • 出版年:   2020

▎ 摘  要

Due to its high capacity (1675 mAh g(-1)), Li-S batteries have been considered as one of the ideal energy storage systems. The grand challenges of lithium-sulfur batteries are sulfur immobilization and improving electrical conductivity of cathode composite. The carbon-sulfur (C-S) composites and the polar materials (Ni(OH)(2), TiO2, MnO2, TiS2, Co9S8, etc) integration have been proven to be two of the most effective routes to achieving good Li-S battery performance. However, each strategy has drawbacks: the C-S composites have low volume density and the polar materials are often lack of electrical conductivity. Therefore, the hybridization of carbon and polar materials shall provide synergistic effects achieving ideal sulfur cathode. Herein, a hybrid material with carbon-coated NiS nanoparticles grown on graphene sheets was synthesized through a hydrothermal reaction followed by two steps of annealing. The obtained composite has a well-balanced ratio between graphene and NiS. An optimized energy density was demonstrated in lithium-sulfur cells.