• 文献标题:   Synergic effect of graphene and core-shells structured Au NR@SiO2@TiO2 in dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   BAI LH, WEN JQ, TANG YW, WU H, ZHANG H, WANG X, HE WL, SUN RJ
  • 作者关键词:   graphene, aunanorod, sio2@tio2 double shell, synergistic effect, composite photoanode, dye sensitized solar cells dsscs
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Xian Shi You Univ
  • 被引频次:   5
  • DOI:   10.1088/1361-6528/ab3b74
  • 出版年:   2019

▎ 摘  要

Graphene and Au nanorods (AuNRs) coated with SiO2@TiO2 double shells (AuNR@SiO2@TiO2 ) were incorporated to form novel composite photoanodes in dye sensitized solar cells (DSSCs). The performances of the photoanodes and DSSCs are studied systematically. The short circuit current density (J(SC)) and power conversion efficiency (PCE) of these composited DSSCs were greatly enhanced and the influences of the graphene, AuNRs and the SiO2@TiO2 double shells were revealed. The optimal properties with the maximal J(SC) of 16.26 mA cm(-2) and PCE of 8.08% are obtained in the DSSC co-doped with graphene and AuNR@SiO2@TiO2, significantly higher than those of the conventional DS SC with pure TiO2 photoanode by 37.7% and 32.9%, respectively. These significant enhancements in J(SC) and PCE are attributed to the synergistic effect of graphene, the local surface plasma resonance of AuNRs, as well as the outer SiO2@TiO2 double shells, which result in the increased specific surface area and dye adsorption, the increased light absorption, the decreased charge transfer resistance R-2 and electron recombination and thus the increased J(SC) and PCE of the DSSCs.